Synthesis of functionalized fulvenes: [3 + 2] annulation of ethyl α-chlorocyclopropaneformates with 1,3-dicarbonyl compounds-Reference-Cited by-同舟云学术

Synthesis of functionalized fulvenes: [3 + 2] annulation of ethyl α-chlorocyclopropaneformates with 1,3-dicarbonyl compounds

Published:2014 Issue:44 Volume:12 Page:8828-8831
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Zhu Yuequan¹²³,Zhang Min¹²³,Yuan Hongling¹²³,Gong Yuefa¹²³

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Huazhong University of Science and Technology

3. Wuhan 430074, China

Abstract

An efficient method is reported to produce acidic multi-substituted fulvenes at high yields (up to 94%) through the base-promoted [3 + 2] annulation reaction of ethyl α-chlorocyclopropaneformates with 1,3-dicarbonyl compounds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB01973C

Reference29 articles.

1. A Two-Step Sequence to Ethyl α-Fluorocyclopropanecarboxylates Through MIRC Reaction of Ethyl Dichloroacetate and Highly Regioselective Fluorination

2. Can Fulvene S1 Decay Be Controlled? A CASSCF Study with MMVB Dynamics

3. Fulvalenes, Fulvenes, and Related Molecules: An ab Initio Study

4. Novel D-π-A Chromophores Based on the Fulvene Accepting Moiety

5. Aromaticity of the Bergman, Myers−Saito, Schmittel, and Directly Related Cyclizations of Enediynes

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