3D microstructural characterization of Ni/yttria-stabilized zirconia electrodes during long-term CO2 electrolysis

Author:

Shang Yijing1,Smitshuysen Anne Lyck12,Yu Miao1,Liu Yuliang13,Tong Xiaofeng4,Jørgensen Peter Stanley1,Rorato Léa5ORCID,Laurencin Jérôme5,Chen Ming1ORCID

Affiliation:

1. Department of Energy Conversion and Storage, Technical University of Denmark, 2800, Kgs. Lyngby, Denmark

2. DynElectro ApS, 4130, Viby Sjaelland, Denmark

3. School of Materials Science and Engineering, Henan University of Science &Technology, 471023, Luoyang, China

4. Institute of Energy Power Innovation, North China Electric Power University, 102206, Beijing, China

5. Univ. Grenoble Alpes - CEA/LITEN, 38054, Grenoble, France

Abstract

Detailed electrochemical and 3D microstructural characterization of Ni/YSZ electrodes confirms that Ni migration also occurs during CO2 electrolysis, most likely driven by the gradient in the Ni–YSZ interfacial energy along the current direction.

Funder

China Scholarship Council

National Natural Science Foundation of China

Energiteknologisk udviklings-og demonstrationsprogram

Innovationsfonden

Cancéropôle Grand Ouest

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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