Mixed H2O/H2 plasma-induced redox reactions of thin uranium oxide films under UHV conditions

Author:

El Jamal Ghada1ORCID,Gouder Thomas2,Eloirdi Rachel2,Tereshina-Chitrova Evgenia34,Horákd Lukáš4,Jonsson Mats1ORCID

Affiliation:

1. School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Department of Chemistry, Applied Physical Chemistry, KTH Royal Institute of Technology, SE-100 44 Stockholm, Sweden

2. European Commission, Joint Research Centre, Postfach 2340, DE-76215 Karlsruhe, Germany

3. Institute of Physics, ASCR, Prague, Czech Republic

4. Faculty of Mathematics and Physics, Charles University, 12116 Prague, Czech Republic

Abstract

X-ray photoelectron spectroscopy (XPS) has been used to study the effect of mixed H2O/H2 gas plasma on the surfaces of UO2, U2O5 and UO3 thin films at 400 °C.

Funder

Svensk Kärnbränslehantering

H2020 Euratom

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference38 articles.

1. Uranium(IV) hydrolysis constants and solubility product of UO2.cntdot.xH2O(am)

2. S. Svensk Kaernbraenslefoersoerjning Ab , Final storage of spent nuclear fuel - KBS-3 , Swedish Nuclear Fuel Supply Co/Div KBS , Sweden , 1983

3. Spent Nuclear Fuel

4. The chemical state of the fission products in oxide fuels

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