Evidence for 5d-σ and 5d-π covalency in lanthanide sesquioxides from oxygen K-edge X-ray absorption spectroscopy-Reference-Cited by-同舟云学术

Evidence for 5d-σ and 5d-π covalency in lanthanide sesquioxides from oxygen K-edge X-ray absorption spectroscopy

Published:2016 Issue:24 Volume:45 Page:9948-9961
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Altman Alison B.¹²³⁴⁵,Pacold Joseph I.⁵⁶³⁴,Wang Jian⁷⁸⁹,Lukens Wayne W.⁵⁶³⁴,Minasian Stefan G.⁵⁶³⁴

Affiliation:

1. Department of Chemistry

2. University of California

3. Berkeley CA 94720

4. USA

5. Chemical Sciences Division

6. Lawrence Berkeley National Laboratory

7. Canadian Light Source

8. Saskatoon

9. Canada

Abstract

The electronic structure in the complete series of stable lanthanide sesquioxides, Ln₂O₃ (Ln = La to Lu, except radioactive Pm), has been evaluated using oxygen K-edge X-ray absorption spectroscopy with a scanning transmission X-ray microscope (STXM).

Funder

Lawrence Berkely National Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00358C

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