Synthesis of the fluorohydridoborate anions [BHF3]− and [1-HF2B-9,12-X2-closo-1,2-C2B10H9]− (X = H, I): deboronation of 1,2- and 1,7-dicarba-closo-dodecaboranes with anhydrous [Me4N]F-Reference-Cited by-同舟云学术

Synthesis of the fluorohydridoborate anions [BHF3]− and [1-HF2B-9,12-X2-closo-1,2-C2B10H9]− (X = H, I): deboronation of 1,2- and 1,7-dicarba-closo-dodecaboranes with anhydrous [Me4N]F

Published:2016 Issue:90 Volume:52 Page:13241-13244
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Duda Katharina¹²³⁴⁵,Himmelspach Alexander¹²³⁴⁵,Landmann Johannes¹²³⁴⁵,Kraus Florian⁶⁷⁸⁹⁵,Finze Maik¹²³⁴⁵

Affiliation:

1. Institut für Anorganische Chemie

2. Institut für nachhaltige Chemie & Katalyse mit Bor (ICB)

3. Julius-Maximilians-Universität Würzburg

4. 97074 Würzburg

5. Germany

6. Anorganische Chemie

7. Fachbereich Chemie

8. Philipps-Universität Marburg

9. 35032 Marburg

Abstract

The [BHF₃]⁻ anion represents the first example of an anion of the series [BH_nF_4−n]⁻ (n = 1–3), which is obtained via deboronation of closo-1,2-C₂B₁₀H₁₂ or closo-1,7-C₂B₁₀H₁₂ with anhydrous [Me₄N]F.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC07711K

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