Catalytic activity of a new dioxidomolybdenum(<scp>vi</scp>) complex with a bipodal N<sub>2</sub>O-donor ligand in sulfur compound oxidation-Reference-Cited by-同舟云学术

Catalytic activity of a new dioxidomolybdenum(vi) complex with a bipodal N₂O-donor ligand in sulfur compound oxidation

Published:2023 Issue:30 Volume:47 Page:14123-14133
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Machado Paula M. A.¹²,Barreto Juliana M.¹,Motta Ramon da S.¹,Rodrigues José Guilherme A.³,de Souza Wladmir F.⁴,Maldonado Igor A. V.³^ORCID,Allão Cassaro Rafael A.³^ORCID,dos Santos Gustavo R. C.⁵,Carneiro Gabriel R. A.⁵,Pereira Henrique M. G.⁵,D’Elia Eliane³,Horn Adolfo⁶^ORCID,Lachter Elizabeth Roditi¹^ORCID

Affiliation:

1. Universidade Federal do Rio de Janeiro, Instituto de Química, Departamento de Química Orgânica, CEP 21941-909, Rio de Janeiro, RJ, Brazil

2. Instituto Federal Fluminense campus Cabo Frio, CEP 28909-971, Cabo Frio, RJ, Brazil

3. Universidade Federal do Rio de Janeiro, Instituto de Química, Departamento de Química Inorgânica, CEP 21941-909, Rio de Janeiro, RJ, Brazil

4. CENPES – Petrobras, Cidade Universitária, Q7. Ilha do Fundão s/n. CEP 21949-900, Rio de Janeiro, RJ, Brazil

5. Universidade Federal do Rio de Janeiro, Instituto de Química, Laboratório Brasileiro de Controle de Dopagem, CEP 21941-598, Rio de Janeiro, RJ, Brazil

6. Universidade Federal de Santa Catarina, Departamento de Química, CEP 88040-900, Florianópolis, SC, Brazil

Abstract

A new dinuclear dioxidomolybdenum(vi) complex [(MoO2)2(BPA)2(μ-O)] was synthesized and evaluated as a catalyst in the reaction involving the oxidation of sulfur compounds.

Funder

CAPES

Conselho Nacional de Desenvolvimento Científico e Tecnológico

FAPERJ

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D2NJ06227E

Reference75 articles.

1. Dioxidomolybdenum(VI) and dioxidouranium(VI) complexes as functional mimic of haloperoxidases catalytic activity in presence of H2O2–KBr–HClO4

2. Oxido-peroxido molybdenum(VI) complexes in catalytic and stoichiometric oxidations

3. Synthesis, X-ray structure and oxidation catalysis of a oxido–peroxido molybdenum(VI) complex with a tridentate Schiff base ligand

4. cis-Dioxo-molybdenum(VI) Schiff base complexes: Synthesis, crystal structure and catalytic performance for homogeneous oxidation of olefins

5. New molybdenum(VI) complexes with thiazole-hydrazone ligand: Preparation, structural characterization, and catalytic applications in olefin epoxidation