B–H⋯π: a nonclassical hydrogen bond or dispersion contact?-Reference-Cited by-同舟云学术

B–H⋯π: a nonclassical hydrogen bond or dispersion contact?

Author:

Fanfrlík Jindřich¹²³,Pecina Adam¹²³,Řezáč Jan¹²³^ORCID,Sedlak Robert¹²³,Hnyk Drahomír⁴⁵³^ORCID,Lepšík Martin¹²³^ORCID,Hobza Pavel¹²³⁶⁷

Affiliation:

1. Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences

2. 166 10 Prague 6

3. Czech Republic

4. Institute of Inorganic Chemistry of the Czech Academy of Sciences

5. v.v.i., 250 68 Husinec-Řež

6. Regional Center of Advanced Technologies and Materials

7. Department of Physical Chemistry

Abstract

Quantum mechanical calculations disprove the attractive electrostatic nature of B–H⋯π motif and define it as dispersion-driven contact.

Funder

Czech Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

Reference48 articles.

1. G. R. Desiraju and T.Steiner, The Weak Hydrogen Bond, Oxford University Press, Oxford, 1999

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