Ruthenium-catalyzed hydrogenation of CO2 as a route to methyl esters for use as biofuels or fine chemicals

Author:

Wang Zheng12345ORCID,Zhao Ziwei12345,Li Yong12345,Zhong Yanxia675,Zhang Qiuyue8910115ORCID,Liu Qingbin12345ORCID,Solan Gregory A.8910115ORCID,Ma Yanping8910115ORCID,Sun Wen-Hua8910115ORCID

Affiliation:

1. Hebei Key Laboratory of Organic Functional Molecules

2. College of Chemistry and Material Science

3. Hebei Normal University

4. Shijiazhuang 050024

5. China

6. Department of Nursing Shijiazhuang Medical College

7. Shijiazhuang 050000

8. Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Science

9. Institute of Chemistry

10. Chinese Academy of Sciences

11. Beijing 100190

Abstract

A novel robust diphosphine–ruthenium(ii) complex has been developed that can efficiently catalyze both the hydrogenation of CO2 to methanol and its in situ condensation with carboxylic acids to give methyl esters.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hebei Province

Agricultural University of Hebei

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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