FeHS vacancies in a Prussian white cathode leads to enhanced FeLS activity and electrode kinetics for boosted K+ storage

Author:

Zi Shun1,Wang Zixing1,Ke Jinlong1,Mo Ying1,Wang Kexuan2,Chen Shi2ORCID,Tang Rui1ORCID,Li Yanhua3,Gao Peng1ORCID,Liu Jilei1ORCID

Affiliation:

1. College of Materials Science and Engineering, Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy, Hunan Province Key Laboratory for Advanced Carbon Materials and Applied Technology, Hunan University, Changsha 410082, China

2. Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, Macau 999078, China

3. School of Materials Science and Engineering, Hunan Institute of Technology, Hengyang 421002, China

Abstract

High-spin Fe vacancies are successfully introduced into the lattice structure of Prussian white by adjusting synthesis temperatures, which facilitates K+ diffusion and stabilizes the host structure, thus resulting in enhanced K+ storage capability.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Natural Science Foundation of Hunan Province

Publisher

Royal Society of Chemistry (RSC)

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