Collision-assisted stripping for determination of microsolvation-dependent protonation sites in hydrated clusters by cryogenic ion trap infrared spectroscopy: the case of benzocaineH+(H2O)n

Author:

Hirata Keisuke123ORCID,Haddad Fuad4,Dopfer Otto34ORCID,Ishiuchi Shun-ichi123ORCID,Fujii Masaaki135ORCID

Affiliation:

1. Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama, 226-8503, Japan

2. Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550, Japan

3. Tokyo Tech World Research Hub Initiative (WRHI), Institute of Innovation Research, Tokyo Institute of Technology, Nagatsuta-cho, Midori-ku, 4259, Yokohama, 226-8503, Japan

4. Institut für Optik und Atomare Physik, Technische Universität Berlin, Hardenbergstrasse 36, Berlin 10623, Germany

5. School of Life Science and Technology, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa, 226-8503, Japan

Abstract

Protonation sites in hydrated clusters can be clearly determined by CAS-IRPD (collision-assisted stripping infrared photodissociation) spectroscopy as shown for the example of hydrated protonated benzocaine.

Funder

RIKEN

Ministry of Education, Culture, Sports, Science and Technology

Tokyo Institute of Technology

Deutsche Forschungsgemeinschaft

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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