Transition-metal interdiffusion and solid electrolyte poisoning in all-solid-state batteries revealed by cryo-TEM-Reference-Cited by-同舟云学术

Transition-metal interdiffusion and solid electrolyte poisoning in all-solid-state batteries revealed by cryo-TEM

Published:2023 Issue:31 Volume:59 Page:4600-4603
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhang Ruizhuo¹^ORCID,Strauss Florian¹,Jiang Lin²,Casalena Lee²,Li Letian³,Janek Jürgen¹⁴^ORCID,Kondrakov Aleksandr¹⁵,Brezesinski Torsten¹^ORCID

Affiliation:

1. Battery and Electrochemistry Laboratory, Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen 76344, Germany

2. Thermo Fisher Scientific, 5350 NE Dawson Creek Drive, Hillsboro, OR 97124, USA

3. Thermo Fisher Scientific, Achtseweg Noord 5, Eindhoven 5651 GG, The Netherlands

4. Institute of Physical Chemistry and Center for Materials Research, Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, Giessen 35392, Germany

5. BASF SE, Carl-Bosch-Str. 38, Ludwigshafen 67056, Germany

Abstract

TEM investigations under cryogenic conditions reveal transition-metal dissolution and interdiffusion into the bulk solid electrolyte in thiophosphate-based all-solid-state batteries.

Funder

BASF

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC00516J

Reference32 articles.

1. A solid future for battery development

2. Interface Stability in Solid-State Batteries

3. Understanding interface stability in solid-state batteries

4. Capacity Fade in Solid-State Batteries: Interphase Formation and Chemomechanical Processes in Nickel-Rich Layered Oxide Cathodes and Lithium Thiophosphate Solid Electrolytes

5. Interfaces and Interphases in All-Solid-State Batteries with Inorganic Solid Electrolytes

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