Electron density effect of aromatic carboxylic acids in naphthalenediimide-based coordination polymers: from thermal electron transfer and charge transfer to photoinduced electron transfer

Author:

Li Gao-Peng1ORCID,Zhang Jing1,Ren Wan-Wan1,Wang Si-Nan1,Wang Ying-Xia1ORCID,Fu Yun-Long1ORCID,Wang Yao-Yu2ORCID

Affiliation:

1. Key Laboratory of Magnetic Molecules and Magnetic Information Materials of the Ministry of Education, School of Chemistry and Material Science, Shanxi Normal University, Taiyuan 030031, China

2. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710127, P. R. China

Abstract

The delicate modulating effect of the electron density of donors on the charge and electron transfer behaviors in electron donor–acceptor coordination polymers under the condition of the HOMO of the donor being located above the LUMO of the acceptor.

Funder

Shanxi Scholarship Council of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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