Synthesis of amine-bridged bis(phenolate) rare-earth metal aryloxides and their catalytic performances for the ring-opening polymerization of l-lactic acid O-carboxyanhydride and l-lactide-Reference-Cited by-同舟云学术

Synthesis of amine-bridged bis(phenolate) rare-earth metal aryloxides and their catalytic performances for the ring-opening polymerization of l-lactic acid O-carboxyanhydride and l-lactide

Published:2017 Issue:45 Volume:46 Page:15928-15938
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ouyang Hao¹²³⁴⁵,Nie Kun¹²³⁴⁵,Yuan Dan¹²³⁴⁵^ORCID,Yao Yingming¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province

2. Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis

3. and State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials

4. College of Chemistry

5. Chemical Engineering and Materials Science

Abstract

Rare-earth metal aryloxides were found as efficient initiators for the ring-opening polymerization of l-lactic acid O-carboxyanhydride and l-lactide. A comparative study on catalyst activities and reaction kinetics were conducted.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03001K

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1. Preparation and properties of absorbable fibres from l-lactide copolymers

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