Experimental and computational preference for phosphine regioselectivity and stereoselective tripodal rotation in HOs3(CO)8(PPh3)2(μ-1,2-N,C-η1,κ1-C7H4NS)-Reference-Cited by-同舟云学术

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Experimental and computational preference for phosphine regioselectivity and stereoselective tripodal rotation in HOs3(CO)8(PPh3)2(μ-1,2-N,C-η1,κ1-C7H4NS)

Published:2018 Issue:57 Volume:8 Page:32672-32683
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Begum Shahin A.¹²³⁴,Chowdhury Md. Arshad H.¹²³⁴,Ghosh Shishir¹²³⁴^ORCID,Tocher Derek A.¹⁵⁶⁷^ORCID,Richmond Michael G.¹⁸⁹¹⁰^ORCID,Yang Li¹⁸⁹¹⁰,Hardcastle K. I.¹¹¹¹²¹⁰,Rosenberg Edward¹¹³¹⁴¹⁰,Kabir Shariff E.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Jahangirnagar University

3. Dhaka-1342

4. Bangladesh

5. University College London

6. London WC1H OAJ

7. UK

8. University of North Texas

9. Denton

10. USA

11. Emory University

12. Atlanta

13. University of Montana

14. Missoula

Abstract

The site preference for PPh₃ substitution in HOs₃(CO)₁₀(PPh₃)₂(μ-1,2-N,C-η¹,κ¹-C₇H₄NS) (1) has been investigated.

Funder

Ministry of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA07400C

Reference85 articles.

1. Potential models of the interactions between nitrogen-containing heterocycles and the active catalyst sites in heterogeneous hydrodenitrogenation catalysts

2. Synthesis of dimetallaazacyclobutenes via reaction of polynuclear heteroaromatic nitrogen compounds with triruthenium dodecacarbonyl: reactivity and structural elucidation

3. New methods for functionalizing biologically important molecules using triosmium metal clusters

4. Molecular Transformations of Bicyclic Nitrogen Heterocycles on Triosmium Clusters

5. Mechanistic and Structural Studies of Electron-Deficient Quinoline Triosmium Clusters

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1. Synthesis, Structure and Fluxional Behaviour of Sulfido-Capped Triruthenium Clusters Containing a Bridging 1,1’-Bis(diphenylphosphino)ferrocene Ligand;Journal of Cluster Science;2024-06-09

2. Synthesis and characterization of µ,κ1- and µ,κ2-dithiolate di- and triruthenium complexes with a dppf ligand [dppf = 1,1'-bis(diphenylphosphino)ferrocene];Inorganica Chimica Acta;2023-06

3. Reactions of diphosphine-stabilized Os₃ clusters with triphenylantimony: syntheses and structures of new antimony-containing Os₃ clusters via Sb–Ph bond cleavage;RSC Advances;2023

4. Synthesis, Structure, and Reactivity of Triosmium Clusters Bearing a Metalated Dialkyl-substituted Pyrazine Ligand;Journal of Chemical Crystallography;2022-09-05

5. New Tri- and Pentanuclear Osmium Clusters from [Os3(CO)10(NCMe)2] and Pyrrolidine: Reactivity and X-ray Structure of [HOs3(CO)9(µ,κ2-N=C(CH3)C=NCH2CH2CH2)] and [H3Os5(CO)14(µ,η1,κ1-N=CCH2CH2CH2)];Journal of Cluster Science;2022-07-11

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