Catalytic methoxylation of aryl halides using 13C- and 14C-labeled CO2-Reference-Cited by-同舟云学术

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Catalytic methoxylation of aryl halides using ¹³C- and ¹⁴C-labeled CO₂

Published:2022 Issue:92 Volume:58 Page:12831-12834
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ohleier Alexia¹²³,Sallustrau Antoine²^ORCID,Mouhsine Bouchaib²,Caillé Fabien³^ORCID,Audisio Davide²^ORCID,Cantat Thibault¹^ORCID

Affiliation:

1. Université Paris-Saclay, CEA, CNRS, NIMBE, Gif-sur-Yvette 91191, France

2. Université Paris-Saclay, Service de Chimie Bio-organique et Marquage (SCBM), CEA/DRF/JOLIOT, Gif sur Yvette 91191, France

3. Université Paris-Saclay, Inserm, CNRS, CEA, Laboratoire d’Imagerie Biomédicale Multimodale Paris-Saclay, Orsay 91401, France

Abstract

A late-stage carbon isotope strategy, which allows methoxylation from CO2, is reported. This catalytic process, that relies on the formation of BBN-OCH3, enabled 13C and 14C labeling of a series of substrates, including pharmaceuticals.

Funder

Agence Nationale de la Recherche

H2020 Marie Skłodowska-Curie Actions

Université Paris-Saclay

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC03746G

Reference47 articles.

1. Boron-mediated activation of carbon dioxide

2. New trends and applications in carboxylation for isotope chemistry

3. Isotope chemistry; a useful tool in the drug discovery arsenal

4. C-11 Radiochemistry in Cancer Imaging Applications

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