A highly elastic polysiloxane-based polymer electrolyte for all-solid-state lithium metal batteries

Author:

Fu Chengyin12345,Iacob Mihail62345,Sheima Yauhen7895,Battaglia Corsin12345,Duchêne Léo12345ORCID,Seidl Lukas12345,Opris Dorina M.62345ORCID,Remhof Arndt12345ORCID

Affiliation:

1. Materials for Energy Conversion

2. Empa

3. Swiss Federal Laboratories for Materials Science and Technology

4. 8600 Dübendorf

5. Switzerland

6. Functional Polymers

7. Ecole Polytechnique Fédérale de Lausanne (EPFL)

8. Institut des Matériaux

9. Lausanne

Abstract

An elastic electrolyte with a Tg = −51 °C, an ionic conductivity of 4.8 × 10−5 S cm−1, and a transference number of 0.53 showed a high initial capacity of 134 mA h g−1 and 75% capacity retention after 150 cycles at 0.1 mA cm−2 at 60 °C in a full cell.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

European Research Council

Horizon 2020

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Reference65 articles.

1. A vision for a sustainable battery value chain in 2030: unlocking the full potential to power sustainable development and climate change mitigation , https://www.weforum.org/reports/a-vision-for-a-sustainable-battery-value-chain-in-2030 , 2019

2. In-depth safety-focused analysis of solvents used in electrolytes for large scale lithium ion batteries

3. Challenges in the development of advanced Li-ion batteries: a review

4. The Li-Ion Rechargeable Battery: A Perspective

5. Thin-film lithium and lithium-ion batteries

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