Temperature-driven n–p conduction type switching without structural transition in a Cu-rich chalcogenide, NaCu5S3

Author:

Qu Shangqing12345ORCID,Wang Yonggang675ORCID,Xiao Yu89105ORCID,Yuan Yujie12345,Li Shengyi1112131415,Chen Jikun12345ORCID,Zhao Lidong89105ORCID,Xia Zhiguo12345,Zhao Jing12345ORCID

Affiliation:

1. The Beijing Municipal Key Laboratory of New Energy Materials and Technologies

2. School of Materials Sciences and Engineering

3. University of Science and Technology Beijing

4. Beijing 100083

5. China

6. Center for High Pressure Science and Technology Advanced Research (HPSTAR)

7. Beijing, 100094

8. School of Materials Science and Engineering

9. Beihang University

10. Beijing 100191

11. CAS Key Laboratory of Molecular Nanostructure and Nanotechnology

12. CAS Research/Education Center for Excellence in Molecular Sciences

13. Institute of Chemistry

14. Chinese Academy of Sciences (CAS)

15. Beijing 100190

Abstract

We report for the first time the discovery of reversible n–p conduction type switching in a chalcogenide, NaCu5S3, without structural transition.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Beijing Municipality

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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