A novel pathway for the thermolysis of N-nitrosoanthranilates using flash vacuum pyrolysis leading to 7-aminophthalides

Author:

Zlatković Dragan12345,Dallinger Doris12345ORCID,Kappe C. Oliver12345ORCID

Affiliation:

1. Institute of Chemistry

2. University of Graz

3. NAWI Graz

4. 8010 Graz

5. Austria

Abstract

Flash vacuum pyrolysis of N-methyl-N-nitrosoanthranilate esters offers a solvent-free route to 7-(methylamino)phthalides via a disproportionation pathway.

Funder

Österreichische Forschungsförderungsgesellschaft

Bundesministerium für Wissenschaft, Forschung und Wirtschaft

Steirische Wirtschaftsförderungsgesellschaft

Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference17 articles.

1. Structural elucidation of thermolysis products of methyl N-methyl-N-nitrosoanthranilate

2. R. F. C. Brown , Pyrolytic Methods in Organic Chemistry: Application of Flow and Flash Vacuum Pyrolytic Techniques , Academic Press , New York, USA , 1980

3. Flash Vacuum Pyrolysis: Techniques and Reactions

4. Exotic Chemistry and Rational Organic Syntheses at 1000 °C

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