Carboxylation of terminal alkynes with CO2 catalyzed by bis(amidate) rare-earth metal amides-Reference-Cited by-同舟云学术

Carboxylation of terminal alkynes with CO2 catalyzed by bis(amidate) rare-earth metal amides

Published:2015 Issue:3 Volume:17 Page:1675-1682
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Cheng Hao¹²³⁴⁵,Zhao Bei¹²³⁴⁵,Yao Yingming¹²³⁴⁵,Lu Chengrong¹²³⁴⁵

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province

2. College of Chemistry

3. Chemical Engineering and Materials Science

4. Dushu Lake Campus

5. Soochow University

Abstract

Three novel bis(amidate) rare-earth metal amides were prepared and characterized. Treatment of CO₂ with terminal alkynes obtained propiolic acids in high to excellent yields using the highest reactive Nd-based catalyst at ambient pressure.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/GC/C4GC02200A

Reference98 articles.

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2. The synthesis of organic carbonates from carbon dioxide

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5. Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?

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