Organocatalytic insertion into C–B bonds by in situ generated carbene: mechanism, role of the catalyst, and origin of stereoselectivity-Reference-Cited by-同舟云学术

Organocatalytic insertion into C–B bonds by in situ generated carbene: mechanism, role of the catalyst, and origin of stereoselectivity

Published:2022 Issue:3 Volume:12 Page:947-953
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Zhang Qiao-Yu¹,Wang Yang²^ORCID,Li Shi-Jun¹^ORCID,Wang Yanyan¹,Wei Donghui¹^ORCID

Affiliation:

1. College of Chemistry, Institute of Green Catalysis, Zhengzhou University, 100 Science Avenue, Zhengzhou 450001, Henan, P. R. China

2. Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, 136 Science Avenue, Zhengzhou 450002, Henan Province, P.R. China

Abstract

The calculated results showed that C–H⋯X (X = I, Br) hydrogen bond interactions should be the determining factors of stereoselectivity, and FMO overlap mode and ELF analyses along IRC results were performed to explore the nature of carbene insertion.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Henan Province

Higher Education Discipline Innovation Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY01232K

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1. Copper-catalyzed oxidative carbon–heteroatom bond formation: a recent update