Mixed amidophenolate–catecholates of molybdenum(vi)-Reference-Cited by-同舟云学术

Mixed amidophenolate–catecholates of molybdenum(vi)

Published:2014 Issue:9 Volume:43 Page:3601-3611
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Shekar Sukesh¹²³⁴,Brown Seth N.¹²³⁴

Affiliation:

1. Department of Chemistry and Biochemistry

2. 251 Nieuwland Science Hall

3. University of Notre Dame

4. Notre Dame, USA

Abstract

Changing two catecholate ligands to amidophenolates tempers the Lewis acidity of tris(catecholato)molybdenum(vi), but seven-coordinate structures are still observed in the pyridine adduct or in a mixed catecholate-bridged dimer.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT53496K

Reference45 articles.

1. Unique properties of transition metal quinone complexes of the MQ3 series

2. Group transfer reactions of d0 transition metal complexes: redox-active ligands provide a mechanism for expanded reactivity

3. Nonclassical oxygen atom transfer reactions of oxomolybdenum(vi) bis(catecholate)

4. Synthesis of tris(3,5-di-tert-butylcatecholato)molybdenum(VI) and its reaction with molecular oxygen

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