Accelerating the insertion reactions of (NHC)Cu–H via remote ligand functionalization-Reference-Cited by-同舟云学术

Accelerating the insertion reactions of (NHC)Cu–H via remote ligand functionalization

Published:2021 Issue:34 Volume:12 Page:11495-11505
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Speelman Amy L.¹^ORCID,Tran Ba L.¹,Erickson Jeremy D.¹,Vasiliu Monica²,Dixon David A.²^ORCID,Bullock R. Morris¹^ORCID

Affiliation:

1. Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99352, USA

2. Department of Chemistry and Biochemistry, University of Alabama, Tuscaloosa, AL 35487, USA

Abstract

Remote modification of an N-heterocyclic carbene ligand with bulky or electron-rich groups in [(NHC)Cu(μ-H)]2 increases the rate of substrate insertion, which kinetics studies suggest arises from changes in the Cu–H monomer–dimer equilibrium.

Funder

U.S. Department of Energy

University of Alabama

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01911B

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