Metal-free hypervalent iodine/TEMPO mediated oxidation of amines and mechanistic insight into the reaction pathways
Author:
Affiliation:
1. Chemical Engineering & Process Development Division
2. CSIR-National Chemical Laboratory
3. Pune-411008
4. India
5. Academy of Scientific and Innovative Research (AcSIR)
Abstract
A highly efficient, metal free rapid protocol studied mechanistically the oxidation of primary and secondary amines to their corresponding carbonyl compounds using PhI(OAc)2and catalytic TEMPO to provide diverse products in excellent yields.
Funder
University Grants Commission
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA07451H
Reference71 articles.
1. G.Tojo and M.Fernandez , Oxidation of Alcohols to Aldehydes and Ketones , Springer , New York , 1st edn, 2006
2. Organocatalytic Oxidations Mediated by Nitroxyl Radicals
3. Yb(OTf)3-Catalyzed Oxidation of Alcohols with Iodosylbenzene Mediated by TEMPO
4. An excellent dual recycling strategy for the hypervalent iodine/nitroxyl radical mediated selective oxidation of alcohols to aldehydes and ketones
5. o-Iodoxybenzoic Acid (IBX) as a Viable Reagent in the Manipulation of Nitrogen- and Sulfur-Containing Substrates: Scope, Generality, and Mechanism of IBX-Mediated Amine Oxidations and Dithiane Deprotections
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