Can low-valent silicon compounds be better transition metal ligands than phosphines and NHCs?

Author:

Benedek Zsolt1234,Szilvási Tibor1234

Affiliation:

1. Department of Inorganic and Analytical Chemistry

2. Budapest University of Technology and Economics

3. 1111 Budapest

4. Hungary

Abstract

We investigated the potential application of low-valent silicon compounds as transition metal ligands by computing the most important ligand properties and compared them to the generally used carbene and phosphine ligands.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference101 articles.

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2. Applications of Transition Metal Catalysis in Drug Discovery and Development, ed. M. L. Crawley and B. M.Trost, Wiley, 2012

3. Ligand electronic effects in homogeneous catalysis using transition metal complexes of phosphine ligands, ed. M. L. Clarke and J. J. R. Frew, RSC Publishing, 2009

4. Phosphorus(III) ligands in homogeneous catalysis: Design and synthesis, ed. P. C. J. Kamer and P. W. N. M. van Leeuwen, Wiley, 2012

5. Homogeneous Catalysis with Metal Phosphine Complexes, ed. L. M. Pignolet, Springer, 2013

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