Poly(methylhydrosiloxane) as a reductant in the catalytic base-free Wittig reaction
Author:
Affiliation:
1. Leibniz Institute for Catalysis at the University of Rostock (LIKAT Rostock)
2. D-18059 Rostock
3. Germany
4. Department of Chemistry and Center for Sustainable Systems Design (CSSD)
5. Paderborn University
Abstract
PMHS proved to be a suitable terminal reductant for P(iii)/P(v) redox cycling with a methyl-substituted phosphetane as catalyst and BuOAc as solvent. The formation of water by silanol condensation was identified as main pathway of siloxane formation.
Funder
Leibniz-Gemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Pollution,Environmental Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/GC/D1GC00953B
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