Electronic nature of zwitterionic alkali metal methanides, silanides and germanides – a combined experimental and computational approach-Reference-Cited by-同舟云学术

Electronic nature of zwitterionic alkali metal methanides, silanides and germanides – a combined experimental and computational approach

Published:2017 Issue:2 Volume:8 Page:1316-1328
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Li H.¹²³⁴,Aquino A. J. A.¹²³⁴,Cordes D. B.¹²³⁴^ORCID,Hase W. L.¹²³⁴,Krempner C.¹²³⁴

Affiliation:

1. Texas Tech University

2. Department of Chemistry and Biochemistry

3. Lubbock

4. USA

Abstract

Zwitterionic group 14 complexes of the alkali metals of formula [E(SiMe₂OCH₂CH₂OMe)₃M], where E = C, Si or Ge and M = Li, Na or K, have been prepared, structurally characterized and their electronic nature was investigated by computational methods.

Funder

National Science Foundation

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC02390H

Reference109 articles.

1. Preparation and crystal structure of the novel internally solvated dimeric organolithium compound [{LiC(SiMe2OMe)3}2]

2. Synthesis, crystal structure and reactions of the dimeric organolithium compound [{[(MeO)Me2Si]3CLi}2]