Ligand-controlled exposure of active sites on the Pd1Ag14 nanocluster surface to boost electrocatalytic CO2 reduction-Reference-Cited by-同舟云学术

Ligand-controlled exposure of active sites on the Pd₁Ag₁₄ nanocluster surface to boost electrocatalytic CO₂ reduction

Published:2024 Issue:23 Volume:60 Page:3162-3165
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ma Along¹²,Ren Yonggang²,Zuo Yang²,Wang Jiawei²,Huang Shutong²,Ma Xiaoshuang²^ORCID,Wang Shuxin¹²^ORCID

Affiliation:

1. Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

2. College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

Abstract

Two nanoclusters, Pd1Ag14-S and Pd1Ag14-E, were synthesized, with the latter exposing an Ag active site. eCO2RR studies showed this exposure markedly improves catalytic selectivity for converting CO2 to CO.

Funder

National Natural Science Foundation of China

Changjiang Scholar Program, Ministry of Education

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00152D

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