Construction of heterometallic clusters with multiple uranium–metal bonds by using dianionic nitrogen–phosphorus ligands

Author:

Feng Genfeng12345,McCabe Karl N.678910,Wang Shuao1112131415ORCID,Maron Laurent678910ORCID,Zhu Congqing12345ORCID

Affiliation:

1. State Key Laboratory of Coordination Chemistry

2. Jiangsu Key Laboratory of Advanced Organic Materials

3. School of Chemistry and Chemical Engineering

4. Nanjing University

5. Nanjing

6. LPCNO

7. CNRS & INSA

8. Université Paul Sabatier

9. Toulouse

10. France

11. State Key Laboratory of Radiation Medicine and Protection

12. School for Radiological and Interdisciplinary Sciences (RAD-X)

13. Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions

14. Soochow University

15. Suzhou

Abstract

Compared with the prevalent metal–metal bond in transition metals, examples of the actinide–metal bond in heterometallic clusters are rare.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference71 articles.

1. R. D. Adams and F. A.Cotton , Catalysis by di- and polynuclear metal cluster complexes , Wiley-VCH , New York , 1998

2. Catalytic Applications of Early/Late Heterobimetallic Complexes

3. J. P. Fackler , Metal – Metal Bonds and Clusters in Chemistry and Catalysis , Springer Science & Business Media , 2013

4. S. T. Liddle , Molecular Metal – Metal Bonds , Wiley-VCH , Weinheim , 2015

5. Selectivity Effects in Bimetallic Catalysis

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