K2MgMoP2O10 and K3Mg2MoP3O14: two new molybdophosphates exhibiting different optical anisotropies induced by variable dimensionality of the anion framework-Reference-Cited by-同舟云学术

K₂MgMoP₂O₁₀ and K₃Mg₂MoP₃O₁₄: two new molybdophosphates exhibiting different optical anisotropies induced by variable dimensionality of the anion framework

Published:2024 Issue:25 Volume:53 Page:10686-10692
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gao Zhixia¹,Feng Qiuyuan¹,Lu Juanjuan²,Du Hong¹³^ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering, Xinjiang Normal University, Urumqi, 830054, P. R. China

2. Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, Xinjiang Key Laboratory of Functional Crystal Materials, Urumqi 830011, China

3. Xinjiang Key Laboratory of Energy Storage and Photoelectrocatalytic Materials, Urumqi, 830054, China

Abstract

Two new molybdophosphates, K2MgMoP2O10 and K3Mg2MoP3O14, were synthesized by spontaneous crystallization. To the best of our acknowledge, K2MgMoP2O10 exhibits the largest birefringence (0.187 at 546 nm) among reported alkali metal or alkaline earth metal molybdophosphates.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Xinjiang Uygur Autonomous Region

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01026D

Reference75 articles.

1. Finding the Next Deep-Ultraviolet Nonlinear Optical Material: NH4B4O6F

2. Toward the ultraviolet (UV) or deep-UV nonlinear optical crystals: The combination of π-conjugated planar [XY3] and tetrahedral [XY4]

3. Fluorooxoborates: Beryllium-Free Deep-Ultraviolet Nonlinear Optical Materials without Layered Growth

4. Crystal Growth and Associated Properties of a Nonlinear Optical Crystal—Ba2Zn(BO3)2

5. Second Harmonic Generation Susceptibilities from Symmetry Adapted Wannier Functions