Light-driven MPV-type reduction of aryl ketones/aldehydes to alcohols with isopropanol under mild conditions

Author:

Cao Dawei123ORCID,Xia Shumei3,Pan Pan2,Zeng Huiying2ORCID,Li Chao-Jun3ORCID,Peng Yong1ORCID

Affiliation:

1. Key Laboratory of Magnetism and Magnetic Materials of the Ministry of Education, School of Physical Science and Technology and Electron Microscopy Centre, Lanzhou University, Lanzhou 730000, P. R. China

2. The State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China

3. Department of Chemistry and FRQNT Centre for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke St. West, Montreal, QC H3A 0B8, Canada

Abstract

A light-driven photocatalyst-free strategy for reducing ketones/aldehydes to alcohols using isopropanol as the reducing agent and solvent in the presence of tBuOLi under mild conditions is developed.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Natural Sciences and Engineering Research Council of Canada

Canada Foundation for Innovation

Fonds Québécois de la Recherche sur la Nature et les Technologies

Canada Research Chairs

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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