Phosphole formation by 1,1-carboboration – reactions of bis-alkynyl phosphanes with a frustrated P/B Lewis pair-Reference-Cited by-同舟云学术

Phosphole formation by 1,1-carboboration – reactions of bis-alkynyl phosphanes with a frustrated P/B Lewis pair

Published:2016 Issue:5 Volume:45 Page:2023-2030
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Klose Annika¹²³,Kehr Gerald¹²³,Daniliuc Constantin G.¹²³,Erker Gerhard¹²³

Affiliation:

1. Organisch-Chemisches Institut

2. 48149 Münster

3. Germany

Abstract

The reaction of arylbis(alkynyl)phosphanes with the frustrated P/B Lewis pair mes₂PCH₂CH₂B(C₆F₅)₂gives phosphane/borane functionalized phospholes by a sequence of 1,1-carboboration reactions.

Funder

European Research Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT03055B

Reference54 articles.

1. Metallacyclopentadienes and related heterocycles via 1,1-organoboration of alkyn-1-ylmetal compounds

2. 1,1-Carboboration

3. Activation of Terminal Alkynes by Frustrated Lewis Pairs

4. Divergent Reactivity of Perfluoropentaphenylborole with Alkynes

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