Cobalt phosphide supported by two-dimensional molybdenum carbide (MXene) for the hydrogen evolution reaction, oxygen evolution reaction, and overall water splitting

Author:

Liu Shilong1,Lin Zongshan1ORCID,Wan Rendian1,Liu Yonggang2,Liu Zhe2,Zhang Shuidong3ORCID,Zhang Xiaofeng4,Tang Zhenghua23ORCID,Lu Xiaoxing1,Tian Yong1

Affiliation:

1. School of Pharmacy, Guangdong Pharmaceutical University, Guangzhou, 510006, P. R. China

2. Guangzhou Key Laboratory for Surface Chemistry of Energy Materials, New Energy Research Institute, School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Center, Guangzhou, Guangdong 510006, China

3. Guangdong Provincial Key Laboratory of Technique and Equipment for Macromolecular Advanced Manufacturing, South China University of Technology, China

4. Institute of New Materials, Guangdong Academy of Science, Guangzhou, 510650, China

Abstract

CoP/Mo2CTx is prepared as efficient catalyst for HER, OER, and water splitting. DFT calculations revealed that it has optimal H* adsorption free energy and MXene plays a critical role to boost HER, while CoP is transformed into Co–OOH in OER.

Funder

Natural Science Foundation of Guangdong Province

Guangzhou Municipal Science and Technology Project

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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