Comparative photo-release of nitric oxide from isomers of substituted terpyridinenitrosylruthenium(ii) complexes: experimental and computational investigations-Reference-Cited by-同舟云学术

Comparative photo-release of nitric oxide from isomers of substituted terpyridinenitrosylruthenium(ii) complexes: experimental and computational investigations

Published:2014 Issue:33 Volume:43 Page:12721-12733
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Akl Joëlle¹²,Sasaki Isabelle¹²,Lacroix Pascal G.¹²,Malfant Isabelle¹²,Mallet-Ladeira Sonia¹²,Vicendo Patricia³⁴⁵,Farfán Norberto⁶⁷⁸⁹,Santillan Rosa¹⁰¹¹¹²¹³

Affiliation:

1. Laboratoire de Chimie de Coordination du CNRS

2. F-31077 Toulouse, France

3. Laboratoire des Interactions Moléculaires et de la Réactivité Chimique et Photochimique

4. Université Paul Sabatier

5. F-31062 Toulouse, France

6. Facultad de Química

7. Departamento de Química Orgánica

8. Universidad Nacional Autónoma de México

9. 04510 México D.F., Mexico

10. Departamento de Química

11. Centro de Investigación y de Estudios del IPN

12. CINVESTAV

13. México, D.F., Mexico

Abstract

Efficient NO photorelease is observed in cis(Cl,Cl)-[Ru^II(FT)Cl₂(NO)](PF₆) and trans(Cl,Cl)-[Ru^II(FT)Cl₂(NO)](PF₆) with a quantum yield of 0.31 and 0.10 respectively.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00974F

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