<i>N</i>-Alkyl substituted triazenide-bridged homoleptic iron(<scp>ii</scp>) dimers with an exceptionally short Fe

N-Alkyl substituted triazenide-bridged homoleptic iron(ii) dimers with an exceptionally short Fe–Fe bond

Published:2024 Issue:4 Volume:53 Page:1439-1444
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Soussi Khaled¹,Jeanneau Erwann²,Maldivi Pascale³^ORCID,Clémancey Martin⁴,Latour Jean-Marc⁴^ORCID,Khrouz Lhoussain⁵,Lorentz Chantal¹,Daniele Stéphane⁶^ORCID,Mishra Shashank¹^ORCID

Affiliation:

1. Université Claude Bernard Lyon 1, CNRS, UMR 5256, Institut de Recherches sur la Catalyse et l'Environnement de Lyon (IRCELYON), 2 avenue Albert Einstein, 69626 Villeurbanne, France

2. Université Claude Bernard Lyon 1, Centre de Diffractométrie Henri Longchambon, 5 rue de La Doua, 69100 Villeurbanne, France

3. Univ. Grenoble Alpes, CEA, CNRS, IRIG, DIESE, SyMMES, F-38000 Grenoble, France

4. Univ. Grenoble Alpes, CEA, CNRS, IRIG, DIESE, LCBM, pmb, F-38000 Grenoble, France

5. Université de Lyon, ENS de Lyon, CNRS, Université Lyon 1, Laboratoire de Chimie, F69342, Lyon, France

6. Université Claude Bernard Lyon 1, CNRS-UMR 5218, CP2M-ESCPE Lyon, 43 Bd du 11 Nov. 1978, 69616, Villeurbanne, France

Abstract

We synthesized novel homoleptic dimeric complexes of the general formula [Fe2(N3tBuR)4] (R = Et, iPr, nBu) having the shortest Fe(ii)–Fe(ii) bond (2.167–2.174 Å) reported to date and a low-spin ground state.

Funder

Ministère de l'Enseignement supérieur, de la Recherche et de l'Innovation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03132B

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