Iron-catalyzed regioselective protoboration of alkenes on N-heterocycles-Reference-Cited by-同舟云学术

Iron-catalyzed regioselective protoboration of alkenes on N-heterocycles

Published:2022 Issue:22 Volume:9 Page:6325-6330
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zou Chenchen¹,Zhang Chun¹²^ORCID

Affiliation:

1. Institute of Molecular Plus, Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Science, Tianjin University, Weijin Rd. 92, Tianjin 300072, China

2. Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, China

Abstract

A novel iron-catalyzed highly regioselective protoboration of alkenes on N-heterocycles has been developed. A series of N-heterocyclic C3-organoborides, each displaying the same skeletal structure as displayed by various pharmaceutical compounds, were accessed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO01293F

Reference58 articles.

1. D.Leonori and V. K.Aggarwal , Reagent-Controlled Lithiation–Borylation , In Synthesis and Application of Organoboron Compounds , ed. E. Fernandez and A. Whiting , Springer International Publishing , Cham , 2015 , pp. 271

2. H.-Y.Sun and D. G.Hall , At the Forefront of the Suzuki−Miyaura Reaction: Advances in Stereoselective Cross Couplings . In Synthesis and Application of Organoboron Compounds , ed. E. Fernandez and A. Whiting , Springer International , Cham, Switzerland , 2015 , pp. 221

3. Asymmetric Synthesis of Secondary and Tertiary Boronic Esters

4. Recent Advances of Applying Boron‐Reagents in Asymmetric Total Syntheses of Natural Products and Bio‐Active Molecules

5. Stereospecific 1,2‐Migrations of Boronate Complexes Induced by Electrophiles