Photoinduced C(sp3)–H sulfination empowers the direct and chemoselective introduction of the sulfonyl group-Reference-Cited by-同舟云学术

Photoinduced C(sp3)–H sulfination empowers the direct and chemoselective introduction of the sulfonyl group

Published:2021 Issue:41 Volume:12 Page:13914-13921
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Jin Shengfei¹,Haug Graham C.¹,Trevino Ramon¹,Nguyen Viet D.¹,Arman Hadi D.¹,Larionov Oleg V.¹^ORCID

Affiliation:

1. Department of Chemistry, The University of Texas at San Antonio, One UTSA Circle, San Antonio, TX, 78249, USA

Abstract

The photoinduced C–H sulfination of abundant aliphatic C–H bonds provides direct access to all major classes of organosulfur compounds via the intermediacy of synthetically versatile sulfinate salts.

Funder

National Institute of General Medical Sciences

National Science Foundation

University of Texas at San Antonio

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC04245A

Reference79 articles.

1. The Chemistry of Sulfinic Acids, Esters and their Derivatives , ed. S. Patai , John Wiley & Sons, Ltd , New Jersey , 1990

2. The Chemistry of Sulfonic Acids, Esters and their Derivatives , ed. S. Patai and Z. Rapport , John Wiley & Sons , New York , 1991

3. Palladium-Catalyzed C−H Bond Functionalization with Arylsulfonyl Chlorides

4. Nickel‐Catalyzed Intermolecular Carbosulfonylation of Alkynes via Sulfonyl Radicals

5. Fine-Tuning Strain and Electronic Activation of Strain-Promoted 1,3-Dipolar Cycloadditions with Endocyclic Sulfamates in SNO-OCTs

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