Ni(2,2′:6′,2′′-terpyridine)<sub>2</sub>: a high-spin octahedral formal Ni(0) complex-Reference-Cited by-同舟云学术

Ni(2,2′:6′,2′′-terpyridine)₂: a high-spin octahedral formal Ni(0) complex

Published:2024 Issue:20 Volume:53 Page:8550-8554
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Cabrera-Lobera Natalia¹,del Horno Estefanía¹,Quirós M. Teresa²^ORCID,Buñuel Elena¹,Gimeno Magali³⁴,Brennessel William W.³^ORCID,Neidig Michael L.⁴^ORCID,Priego José Luis⁵,Cárdenas Diego J.¹^ORCID

Affiliation:

1. Department of Organic Chemistry, Facultad de Ciencias, Universidad Autónoma de Madrid, Institute for Advanced Research in Chemical Sciences (IAdChem), Red ORFEO-CINQA, Av. Francisco Tomás y Valiente 7, Campus de Cantoblanco, 28049, Madrid, Spain

2. Department of Organic Chemistry and Inorganic Chemistry, Facultad de Farmacia, Universidad de Alcalá de Henares, Campus Universitario, 28871, Madrid, Spain

3. Department of Chemistry, University of Rochester, Rochester, New York 14627, USA

4. Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford OX1 3QR, UK

5. Department of Inorganic Chemistry, Universidad Complutense de Madrid, Ciudad Universitaria, 28040, Madrid, Spain

Abstract

Novel Ni(tpy)2 is an octahedral highly paramagnetic complex. Magnetic measurements and DFT calculations suggest intermolecular antiferromagnetic coupling in the solid state.

Funder

Ministerio de Ciencia, Innovación y Universidades

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT04247B

Reference52 articles.

1. Nickel-Catalyzed Dicarbofunctionalization of Alkenes

2. Nickel-Catalyzed Enantioselective Reductive Cross-Coupling Reactions

3. Recent advances in homogeneous nickel catalysis

4. Complexes of Ni(i): a “rare” oxidation state of growing importance

5. Nickel-catalyzed cross coupling of non-activated alkyl halides: a mechanistic perspective