Hydroperoxo double hydrogen bonding: stabilization of hydroperoxo complexes exemplified by triphenylsilicon and triphenylgermanium hydroperoxides-Reference-Cited by-同舟云学术

Hydroperoxo double hydrogen bonding: stabilization of hydroperoxo complexes exemplified by triphenylsilicon and triphenylgermanium hydroperoxides

Published:2020 Issue:11 Volume:22 Page:1922-1928
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Medvedev Alexander G.¹²³⁴^ORCID,Grishanov Dmitry A.¹²³⁴⁵^ORCID,Churakov Andrei V.¹²³⁴^ORCID,Mikhaylov Alexey A.¹²³⁴^ORCID,Lev Ovadia⁵⁶⁷⁸⁹^ORCID,Prikhodchenko Petr V.¹²³⁴^ORCID

Affiliation:

1. Kurnakov Institute of General and Inorganic Chemistry

2. Russian Academy of Sciences

3. Moscow 119991

4. Russia

5. The Casali Center

6. the Institute of Chemistry and The Harvey M. Krueger Family Center for Nanoscience and Nanotechnology

7. The Hebrew University of Jerusalem

8. Jerusalem 91904

9. Israel

Abstract

Triphenylsilicon and germanium hydroperoxo complexes were characterized by single crystal X-ray analysis revealing hydroperoxo double hydrogen bonding.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CE/C9CE01882D

Reference57 articles.

1. One oxidant, many pathways: a theoretical perspective of monooxygenation mechanisms by cytochrome P450 enzymes

2. Reactivity patterns of cytochrome P450 enzymes: multifunctionality of the active species, and the two states–two oxidants conundrum

3. The bioinorganic chemistry of iron in oxygenases and supramolecular assemblies