Experimental and theoretical studies of Si–Cl and Ge–Cl σ-bond activation reactions by iridium-hydride-Reference-Cited by-同舟云学术

Experimental and theoretical studies of Si–Cl and Ge–Cl σ-bond activation reactions by iridium-hydride

Published:2016 Issue:18 Volume:45 Page:7570-7580
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kameo H.¹²³⁴⁵,Ikeda K.¹²³⁴⁵,Sakaki S.⁶⁷⁸⁵,Takemoto S.¹²³⁴⁵,Nakazawa H.¹²⁹⁵,Matsuzaka H.¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Osaka Prefecture University

4. Sakai

5. Japan

6. Fukui Institute for Fundamental Chemistry

7. Kyoto University

8. Kyoto 606-8103

9. Osaka City University

Abstract

We report the iridium hydride-mediated Si–Cl and Ge–Cl σ-bond activation in a low-polarity toluene solution owing to diphosphine-chelation, in which the Si–Cl and Ge–Cl σ-bonds are readily cleaved through an S_N2-type pathway via the formation of a free chloride anion.

Funder

Japan Society for the Promotion of Science

Ministry of Education, Culture, Sports, Science, and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00003G

Reference78 articles.

1. Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution

2. Alkane C–H activation and functionalization with homogeneous transition metal catalysts: a century of progress—a new millennium in prospect