Stereodivergent Pd/Cu catalysis: asymmetric alkylation of racemic symmetrical 1,3-diphenyl allyl acetates-Reference-Cited by-同舟云学术

Stereodivergent Pd/Cu catalysis: asymmetric alkylation of racemic symmetrical 1,3-diphenyl allyl acetates

Published:2021 Issue:9 Volume:19 Page:1955-1959
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Zhao Ling¹²³⁴⁵,Li Guanlin⁴⁵⁶⁷⁸,He Rui⁴⁵⁶⁷⁸,Liu Penglin⁴⁵⁶⁷⁸,Wang Feijun¹²³,Huo Xiaohong⁴⁵⁶⁷⁸,Zhao Min¹²³,Zhang Wanbin¹²³⁹¹⁰^ORCID

Affiliation:

1. East China University of Science and Technology

2. Shanghai 200237

3. China

4. Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs

5. Frontiers Science Center for Transformative Molecules

6. School of Chemistry and Chemical Engineering

7. Shanghai Jiao Tong University

8. Shanghai 200240

9. College of Chemistry and Molecular Engineering

10. Zhengzhou University

Abstract

A stereodivergent Pd/Cu catalyst system was developed, which was successfully applied to the asymmetric allylic alkylation of symmetrical 1,3-disubstituted allyl acetates with prochiral imino esters in a fully stereodivergent manner.

Funder

Shanghai Municipal Education Commission

Science and Technology Commission of Shanghai Municipality

China Postdoctoral Science Foundation

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D0OB02499F

Reference62 articles.

1. Asymmetric Transition Metal-Catalyzed Allylic Alkylations

2. PhosphinooxazolinesA New Class of Versatile, Modular P,N-Ligands for Asymmetric Catalysis

3. Enantioselective Tsuji Allylations

4. Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

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