Acid-catalyzed oxidative cleavage of S–S and Se–Se bonds with DEAD: efficient access to sulfides and selenides-Reference-Cited by-同舟云学术

Acid-catalyzed oxidative cleavage of S–S and Se–Se bonds with DEAD: efficient access to sulfides and selenides

Published:2018 Issue:24 Volume:5 Page:3557-3561
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

An Rui¹²³⁴⁵,Liao Lihao¹²³⁴⁵,Liu Xiang¹²³⁴⁵,Song Shuqin⁶³⁴⁵,Zhao Xiaodan¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Organic Chemistry & MOE Key Laboratory of Bioinorganic and Synthetic Chemistry

2. School of Chemistry

3. Sun Yat-Sen University

4. Guangzhou 510275

5. P. R. China

6. School of Materials Science and Engineering

Abstract

An acid/DEAD system for oxidative cleavage of S–S and Se–Se bonds to generate chalcogenium ions has been developed. These ions could be captured by nucleophile-tethered alkenes and nucleophilic aryl reagents such as arylboronic acids and arenes to give chalcogenides.

Funder

Sun Yat-sen University

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/QO/C8QO00909K

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