A copper(ii)-catalyzed three-component reaction of aryldiazonium tetrafluoroborates, sulfur dioxide, with alkenes-Reference-Cited by-同舟云学术

A copper(ii)-catalyzed three-component reaction of aryldiazonium tetrafluoroborates, sulfur dioxide, with alkenes

Published:2016 Issue:11 Volume:3 Page:1498-1502
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Mao Runyu¹²³⁴⁵,Yuan Zheng⁴⁵⁶³,Zhang Rui⁴⁵⁶³,Ding Yechun¹²³,Fan Xiaona¹²³,Wu Jie⁴⁵⁶³⁷

Affiliation:

1. Gannan Medical University Collaborative Innovation Center for Gannan Oil-tea Camellia Industrial Development

2. Ganzhou

3. China

4. Department of Chemistry

5. Fudan University

6. Shanghai 200433

7. State Key Laboratory of Organometallic Chemistry

Abstract

A three-component reaction of aryldiazonium tetrafluoroborates, sulfur dioxide, with alkenes catalyzed by copper(ii) bromide is developed, which provides an efficient route to (E)-alkenyl sulfones or allylic sulfones via the insertion of sulfur dioxide.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/QO/C6QO00350H

Reference85 articles.

1. Fixation of sulfur dioxide into small molecules

2. Taming sulfur dioxide: a breakthrough for its wide utilization in chemistry and biology

3. A copper(i)-catalyzed three-component reaction of triethoxysilanes, sulfur dioxide, and alkyl halides

4. A palladium-catalyzed three-component coupling of arylboronic acids, sulfur dioxide and hydrazines

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