Perhydrohelicenes and other diamond-lattice based hydrocarbons: the choreography of inversion

Author:

Alder Roger W.1234ORCID,Butts Craig P.1234ORCID,Sessions Richard B.5234ORCID

Affiliation:

1. School of Chemistry

2. University of Bristol

3. Bristol

4. UK

5. School of Biochemistry

Abstract

Overall inversion in fused cyclohexane oligomers 2, 3, and 4 (all based on cis-decalin 1) occurs by a rolling process involving no more than two adjacent rings in twist-boat conformations at any time.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference26 articles.

1. E. L. Eliel , S. H.Wilen and L.Mander, Stereochemistry of Organic Compounds, John Wiley & Sons, 1994, p. 686ff

2. The conformation of the steroid nucleus

3. Empirical force field calculations. 10. Conformational analysis of cis-decalin

4. Why the Standard B3LYP/6-31G* Model Chemistry Should Not Be Used in DFT Calculations of Molecular Thermochemistry: Understanding and Correcting the Problem

5. P. Vanhee , F.de Pessemier, M.Anteunis and D.Tavernier, Recueil des Travaux Chimiques des Pays-Bas, 1979, vol. 98, p. 5

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