Icosahedral carboranes as scaffolds for congested regioselective polyaryl compounds: the distinct distance tuning of C–C and its antipodal B–B

Author:

Kelemen Zsolt1234ORCID,Pepiol Ariadna1234,Lupu Marius1234,Sillanpää Reijo5678,Hänninen Mikko M.5678ORCID,Teixidor Francesc1234ORCID,Viñas Clara1234ORCID

Affiliation:

1. Institut de Ciència de Materials de Barcelona

2. ICMAB-CSIC Campus U.A.B.

3. 08193 Bellaterra

4. Spain

5. Department of Chemistry

6. University of Jyväskylä

7. Jyväskylä

8. Finland

Abstract

Four-fold dense precisely defined patterns of substitution in o-carborane have been demonstrated by experimentation and computed.

Funder

Generalitat de Catalunya

Ministerio de Economía y Competitividad

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference37 articles.

1. R. N. Grimes , Carboranes , Elsevier Inc , New York , 3rd edn, 2016

2. Supramolecular assemblies of globular main group cage species

3. The medicinal chemistry of carboranes

4. Multidentate carborane-containing Lewis acids and their chemistry: mercuracarborands

5. M. A. Fox , Polyhedral Carboranes , in Comprehensive Organometallic Chemistry III , ed. R. H. Crabtree and D. M. P. Mingos , Elsevier , Oxford , 2007 , ch. 3.02, vol. 3, pp. 49–112

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