Substituent effects on paratropicity and diatropicity in π-extended hexapyrrolohexaazacoronene-Reference-Cited by-同舟云学术

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Substituent effects on paratropicity and diatropicity in π-extended hexapyrrolohexaazacoronene

Published:2023 Issue:25 Volume:14 Page:7036-7043
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Takase Masayoshi¹²^ORCID,Takata Toranosuke¹,Oki Kosuke¹,Mori Shigeki²³^ORCID,Uno Hidemitsu¹

Affiliation:

1. Graduate School of Science and Engineering, Ehime University, Matsuyama 790-8577, Japan

2. Research Unit on Molecular Materials Science for Toroidal π-Electron Systems, Ehime University, Matsuyama 790-8577, Japan

3. Advanced Research Support Center (ADRES), Ehime University, Matsuyama 790-8577, Japan

Abstract

Substituent effects in antiaromatic homoHPHAC+ and aromatic homoHPHAC3+ were investigated by NMR, crystal structure, redox, absorption, and DFT calculation analyses.

Funder

Japan Society for the Promotion of Science

Takahashi Industrial and Economic Research Foundation

Tokyo Ohka Foundation for The Promotion of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC07037E

Reference49 articles.

1. Introduction: Aromaticity

2. M.Solà , A. I.Boldyrev , M. K.Cyrański , T. M.Krygowski and G.Merino , Aromaticity and Antiaromaticity , Wiley-VCH , 2023

3. Aromaticity , ed. I. Fernández , Elsevier , 2021

4. R.Gleiter and G.Haberhauer , Aromaticity and Other Conjugation Effects , Wiley-VCH , 2012

5. On the relations between aromaticity and substituent effect

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