Rh-catalyzed reagent-free ring expansion of cyclobutenones and benzocyclobutenones
Author:
Affiliation:
1. The University of Texas at Austin
2. Department of Chemistry
3. Austin
4. USA
5. Department of Chemical Development
6. Boehringer Ingelheim Pharmaceuticals, Inc.
7. Ridgefield
Abstract
A reagent-free Rh-catalyzed ring-expansion reaction via C–C cleavage of cyclobutenones and benzocyclobutenones is reported.
Funder
National Institute of General Medical Sciences
Cancer Prevention and Research Institute of Texas
Welch Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01875G
Reference68 articles.
1. C. D. Gutsche and D.Redmore , in Carbocyclic Ring Expansion Reaction (Advances in Alicyclic Chemical Supplement) , Academic Press , New York , 1968 , p. 81
2. Sulfur-mediated ring expansions in total synthesis
3. Free radical-mediated ring expansion and related annulations
4. Expansion to Seven-Membered Rings
5. Synthetic Organic Chemistry Based on Small Ring Compounds
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