Phosphine-catalyzed [3 + 2] annulation of 2-aminoacrylates with allenoates and mechanistic studies-Reference-Cited by-同舟云学术

Phosphine-catalyzed [3 + 2] annulation of 2-aminoacrylates with allenoates and mechanistic studies

Published:2020 Issue:12 Volume:10 Page:3959-3964
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Wu Xiao-Yun¹²³⁴⁵,Gui Hou-Ze¹²³⁴⁵,Jangra Harish⁶⁷⁸⁹,Wei Yin¹⁰¹¹¹²¹³¹⁴^ORCID,Zipse Hendrik⁶⁷⁸⁹^ORCID,Shi Min¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory for Advanced Materials and Institute of Fine Chemicals

2. School of Chemistry & Molecular Engineering

3. East China University of Science and Technology

4. 200237 Shanghai

5. China

6. Department Chemie

7. Ludwig-Maximilians-Universität München

8. 81377 München

9. Germany

10. State Key Laboratory of Organometallic Chemistry

11. Center for Excellence in Molecular Synthesis

12. University of Chinese Academy of Sciences

13. Shanghai Institute of Organic Chemistry

14. Chinese Academy of Sciences

Abstract

A phosphine catalyzed formal [3 + 2] annulation was disclosed, affording 3-pyrrolines containing an amino quaternary stereogenic center in good to excellent yields. The catalytic mechanism was investigated by DFT and kinetic studies.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Fundamental Research Funds for the Central Universities

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CY/D0CY00092B

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