An unusual co-crystal [(μ2-dcpm)Ag2(μ2-O2CH)(η2-NO3)]2·[(μ2-dcpm)2Ag4(μ2-NO3)4] and its connection to the selective decarboxylation of formic acid in the gas phase
Author:
Affiliation:
1. School of Chemistry and Bio21 Institute of Molecular Science and Biotechnology
2. The University of Melbourne
3. Melbourne
4. Australia
Abstract
Binuclear silver cluster with μ2-formate and μ2-dcpm catalyses the decomposition of HCO2H. This structural motif is present in the crystal.
Funder
Australian Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT03700C
Reference47 articles.
1. Formic acid as a hydrogen source – recent developments and future trends
2. Carbon dioxide and formic acid—the couple for environmental-friendly hydrogen storage?
3. Unimolecular Decomposition of Formic Acid in the Gas PhaseOn the Ratio of the Competing Reaction Channels
4. Computational Study on the Kinetics and Mechanisms for the Unimolecular Decomposition of Formic and Oxalic Acids
5. Catalytic Generation of Hydrogen from Formic acid and its Derivatives: Useful Hydrogen Storage Materials
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