Visible light-induced synthesis of (Z)-β-iodoenamides from N-vinyl amides mediated by the ion pair charge transfer state

Author:

Sun Rui1,Yang Xiao1,Ge Yi-Cen2ORCID,Zheng Xue-Li1ORCID,Yuan Mao-Lin1,Li Rui-Xiang1,Fu Hai-Yan1ORCID,Chen Hua1

Affiliation:

1. Key Laboratory of Green Chemistry & Technology, Ministry of Education College of Chemistry, Sichuan University, Chengdu 610064, P. R. China

2. College of Materials, Chemistry and Chemical Engineering, Chengdu University of Technology, Chengdu, , Sichuan 610059, P. R. China

Abstract

A facile and novel approach for the highly chemo- and stereoselective synthesis of (Z)-β-iodoenamides from N-vinyl amides has been developed based on a visible-light-induced ion pair charge transfer state derived from pyridinium iodides.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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