Anion-promoted CB[6] macromolecule dissolution for stable Zn-ion batteries

Author:

Yang Xiaodong12,Zhao Yuwei32,Lv Shuangkun2,Zhong Leheng2,Yue Chencheng2ORCID,Zhan Shuai2,Zhao Linwei2,Wang Chunfang2,Li Xuejin4,Liu Xiaoya1,Tang Zijie2,Zhang Chunsun1ORCID,Zhi Chunyi32ORCID,Lv (Lyu) Haiming32ORCID

Affiliation:

1. MOE Key Laboratory of Laser Life Science & Institute of Laser Life Science, College of Biophotonics, South China Normal University, Guangzhou 510631, China

2. Songshan Lake Materials Laboratory, Dongguan, Guangdong 523808, China

3. Department of Materials Science and Engineering, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong 999077, China

4. State Key Laboratory of Heavy Oil Processing, School of Materials Science and Engineering, China University of Petroleum, Qingdao 266580, P. R. China

Abstract

CB[6] not only forms complexes with SO42− anions to enhance its solubility, but also adsorbs horizontally on the Zn surface to form an H2O/SO42− shielding layer and induces epitaxial deposition of Zn2+ along the (002) lattice plane.

Funder

Basic and Applied Basic Research Foundation of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

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